Science Olympiad Thermodynamics Practice Test

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What does the second law of thermodynamics state?

Entropy of an isolated system can increase.

Entropy of an isolated system can decrease.

The second law of thermodynamics primarily addresses the concept of entropy in thermodynamic processes. It states that the entropy of an isolated system will always tend to increase over time, or at best remain constant in reversible processes. This reflects the natural tendency towards disorder, which is a fundamental aspect of thermodynamic systems.

In an isolated system, processes occur in such a way that they lead to an increase in overall entropy, meaning that energy becomes more dispersed and organized states tend to transition into less organized ones. This is why the statement focusing on the increase of entropy in an isolated system aligns with the principle outlined in the second law.

The idea that entropy can decrease is fundamentally at odds with the second law, as it suggests a spontaneous movement toward greater order, which is statistically improbable in an isolated system. The possibility of fully converting energy into work is not supported by the second law either, as some energy is always lost to entropy, typically as waste heat. Finally, the statement regarding heat transfer describes a phenomenon where heat flows from hot to cold, reinforcing the unlikeliness of spontaneous heat transfer in the reverse direction without external work, which also aligns with the second law.

Therefore, the correct understanding of the second law lies in acknowledging that the entropy of

Energy can be fully converted to work.

Heat cannot flow from cold to hot spontaneously.

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